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To 1.00 L of a 0.100 M aqueous solution of benzoic acid (C6H5COOH) is added 1.00 mL of 12.0 M HCl. What is the percentage ionization of the benzoic acid in the resulting solution? [Ka(C6H5COOH) = 6.5 * 10-5]


A) 3.3%
B) 12%
C) 1.3%
D) 0.52%
E) 0.065%

F) A) and D)
G) D) and E)

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Acid dissociation constants for phosphoric acid are given below. Acid dissociation constants for phosphoric acid are given below.   A buffer with a pH = 7.4 can best be made by using A) H<sub>3</sub>PO<sub>4</sub> and NaH<sub>2</sub>PO<sub>4</sub>. B) NaH<sub>2</sub>PO<sub>4</sub><sup> </sup>and Na<sub>2</sub>HPO<sub>4</sub>. C) Na<sub>2</sub>HPO<sub>4</sub> and Na<sub>3</sub>PO<sub>4</sub>. D) only NaH<sub>2</sub>PO<sub>4</sub>. E) only Na<sub>2</sub>HPO<sub>4</sub>. A buffer with a pH = 7.4 can best be made by using


A) H3PO4 and NaH2PO4.
B) NaH2PO4 and Na2HPO4.
C) Na2HPO4 and Na3PO4.
D) only NaH2PO4.
E) only Na2HPO4.

F) B) and D)
G) None of the above

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A mixture made from 10 mL of 1 M HCl and 20 mL of 1 M CH3COONa would be classified as a buffer solution.

A) True
B) False

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All indicators are weak acids that are one color in acidic solution and another color in basic solution.

A) True
B) False

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False

Will a precipitate of magnesium fluoride form when 300. mL of 1.1 * 10-3 M MgCl2 are added to 500. mL of 1.2 * 10-3 M NaF? [Ksp (MgF2) = 6.9 * 10-9]


A) Yes, Q > Ksp
B) No, Q < Ksp
C) No, Q = Ksp
D) Yes, Q < Ksp

E) B) and D)
F) A) and D)

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Calculate the minimum concentration of Cr3+ that must be added to 0.095 M NaF in order to initiate a precipitate of chromium(III) fluoride. (For CrF3 , Ksp = 6.6 * 10-11.)


A) 0.023 M
B) 0.032 M
C) 7.7 * 10-8 M
D) 2.9 * 10-9 M
E) 6.9 * 10-10 M

F) A) and E)
G) A) and C)

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Will a precipitate of AgCl form when 0.050 mol NaCl(s)and 0.050 mol AgNO3(s)are dissolved in 500. mL of 3.0 M NH3? [Kf for Ag(NH3)2+ is 1.5 * 107; Ksp(AgCl)= 1.6 * 10-10]

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Write an equation showing the net reaction that occurs when a strong base is added to a CO32-/HCO3- buffer solution (for carbonic acid, Ka1 = 4.2 * 10-7, Ka2 = 2.4 * 10-8):

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HCO3...

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Describe how to prepare 500. mL of a cyanic acid (HCNO)/sodium cyanate (NaCNO)buffer having a pH of 4.80. [Ka(HCNO)= 2.0 * 10-4]

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Dissolve amounts of the two compounds eq...

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Describe how to make a sodium formate (HCOONa)/formic acid (HCOOH)buffer that has a pH of 4.77.

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Prepare a solution h...

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Calculate the pH of a buffer solution prepared by dissolving 0.20 mole of cyanic acid (HCNO) and 0.80 mole of sodium cyanate (NaCNO) in enough water to make 1.0 liter of solution. [Ka(HCNO) = 2.0 * 10-4]


A) 0.97
B) 3.10
C) 4.40
D) 3.70
E) 4.30

F) None of the above
G) D) and E)

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Which response has both answers correct? Will a precipitate form when 250 mL of 0.33 M Na2CrO4 are added to 250 mL of 0.12 M AgNO3? [Ksp(Ag2CrO4) = 1.1 * 10-12] What is the concentration of the silver ion remaining in solution?


A) Yes, [Ag+] = 2.9 * 10-6 M.
B) Yes, [Ag+] = 0.060 M.
C) Yes, [Ag+] = 1.3 * 10-4 M.
D) No, [Ag+] = 0.060 M.
E) No, [Ag+] = 0.105 M.

F) B) and D)
G) C) and E)

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A

Calculate the pH at the equivalence point for the titration of 0.20 M HCl with 0.20 M NH3 (Kb = 1.8 * 10-5) .


A) 2.87
B) 4.98
C) 5.12
D) 7.00
E) 11.12

F) B) and C)
G) A) and D)

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C

Calculate the pH of the solution resulting from the addition of 10.0 mL of 0.10 M NaOH to 50.0 mL of 0.10 M HCN (Ka = 4.9 * 10-10) solution.


A) 5.15
B) 8.71
C) 5.85
D) 9.91
E) 13.0

F) A) and E)
G) A) and C)

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Calculate the concentration of chloride ions in a saturated lead(II) chloride (Ksp = 2.4 * 10-4) solution.


A) 2.4 * 10-4 M
B) 4.8 * 10-4 M
C) 3.9 * 10-2 M
D) 1.2 * 10-1 M
E) 7.8 * 10-2 M

F) A) and B)
G) None of the above

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What is the pH at the equivalence point in the titration of 100 mL of 0.10 M HCN (Ka = 4.9 * 10-10) with 0.10 M NaOH?


A) 3.0
B) 6.0
C) 7.0
D) 11.0
E) 12.0

F) A) and B)
G) A) and C)

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The solubility of strontium carbonate is 0.0011 g/100 mL at 20oC. Calculate the Ksp value for this compound.


A) 7.5 * 10-5
B) 1.5 * 10-4
C) 5.6 * 10-9
D) 7.5 * 10-6
E) 1.5 * 10-3

F) A) and D)
G) C) and E)

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The solubility product for chromium(III) fluoride is Ksp = 6.6 * 10-11. What is the molar solubility of chromium(III) fluoride?


A) 1.6 * 10-3 M
B) 1.2 * 10-3 M
C) 6.6 * 10-11 M
D) 2.2 * 10-3 M
E) 1.6 * 10-6 M

F) A) and B)
G) A) and C)

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The solubility of Ba(NO3)2 is 130.5 g/L at 0oC. How many moles of dissolved salt are present in 4.0 L of a saturated solution of Ba(NO3)2 at 0oC?

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You have 500.0 mL of a buffer solution containing 0.20 M acetic acid (CH3COOH) and 0.30 M sodium acetate (CH3COONa) . What will the pH of this solution be after the addition of 20.0 mL of 1.00 M NaOH solution? [Ka = 1.8 * 10-5]


A) 4.41
B) 4.74
C) 4.56
D) 4.92
E) 5.07

F) B) and D)
G) A) and E)

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