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The meniscus for water is curved upward at the edges (i.e., it is "concave up") because adhesion of water to glass is stronger than cohesion within water.

A) True
B) False

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Indicate all the types of intermolecular forces of attraction in F2(l) .


A) Dispersion and Dipole-dipole
B) Dipole-dipole and Ionic
C) Ion-dipole
D) Hydrogen bonding
E) Dispersion

F) A) and B)
G) A) and C)

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Which of the following would be expected to have the lowest vapor pressure at room temperature


A) ethanol, bp = 78 \circ C
B) methanol, bp = 65 \circ C
C) water, bp = 100 \circ C
D) acetone, bp = 56 \circ C

E) All of the above
F) B) and C)

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Arrange the following in order of increasing boiling point: RbCl, CH3Cl, CH3OH, CH4.


A) CH3OH < CH3Cl < RbCl < CH4
B) CH3OH < CH4 < CH3Cl < RbCl
C) RbCl < CH3Cl < CH3OH < CH4
D) CH4 < CH3OH < CH3Cl < RbCl
E) CH4 < CH3Cl < CH3OH < RbCl

F) B) and C)
G) All of the above

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C5H12 is more viscous than C5H10(OH)2.

A) True
B) False

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Copper crystallizes in a face-centered cubic unit cell. The density of copper is 8.94 g/cm3. Calculate the length of the edge of the unit cell in pm.


A) 461 pm
B) 361 pm
C) 261 pm
D) 161 pm
E) None of the above

F) C) and E)
G) None of the above

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The molar heat of vaporization ( Δ\Delta Hvap) of H2Se is greater than H2O.

A) True
B) False

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Glass is classified as a/an


A) metallic crystal.
B) covalent solid.
C) molecular crystal.
D) amorphous solid.
E) ionic crystal.

F) A) and D)
G) D) and E)

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Which of the following characteristics indicates the presence of weak intermolecular forces in a liquid


A) a low heat of vaporization
B) a high critical temperature
C) a low vapor pressure
D) a high boiling point
E) None of the above.

F) B) and C)
G) A) and B)

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Arrange the following substances in order of increasing boiling point: CH3CH2OH, HOCH2CH2OH, CH3CH2Cl, and ClCH2CH2OH


A) CH3CH2OH < HOCH2CH2OH < CH3CH2Cl < ClCH2CH2OH
B) CH3CH2Cl < CH3CH2OH < ClCH2CH2OH < HOCH2CH2OH
C) CH3CH2OH < CH3CH2Cl < HOCH2CH2OH < ClCH2CH2OH
D) CH3CH2Cl < ClCH2CH2OH < CH3CH2OH < HOCH2CH2OH
E) CH3CH2OH < ClCH2CH2OH < CH3CH2Cl < HOCH2CH2OH

F) C) and D)
G) None of the above

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Identify the dominant (strongest) type of intermolecular force present in Cl2(l) .


A) Dispersion
B) Dipole-dipole
C) Ion-dipole
D) Hydrogen bonding
E) Ionic

F) All of the above
G) A) and D)

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Octane is a liquid component of gasoline. Given the following vapor pressures of octane at various temperatures, estimate the boiling point of octane in Leadville, Colorado, where the atmospheric pressure is 496 mmHg.400 mmHg @ 104 \circ C, 500 mmHg @ 111 \circ C, 600 mmHg @ 117 \circ C, 700 mmHg @ 122 \circ C, 760 mmHg @ 125 \circ C


A) 125 \circ C
B) 120 \circ C
C) 115 \circ C
D) 110 \circ C
E) 105 \circ C

F) A) and B)
G) C) and D)

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Sodium iodide, NaI, melts at 651 \circ C. In its liquid state NaI conducts electricity. What kind of crystal is this


A) Ionic Crystal
B) Covalent Crystal
C) Metallic Crystal
D) Molecular Crystal
E) Amorphous (Not a regular crystal)

F) A) and B)
G) A) and C)

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The mineral manganosite, manganese(II) oxide, crystallizes in the rock salt structure (the face-centered structure adopted by NaCl) with a density of 5.365 g/cm3. Find the unit cell edge length of manganosite.


A) 280.0 pm
B) 352.8 pm
C) 368.2 pm
D) 417.9 pm
E) 444.5 pm

F) B) and E)
G) All of the above

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Ethanol has a higher boiling point than dimethyl ether. (Ethanol and dimethyl ether have the same molecular formula, C2H6O. Their structural formulas are, respectively, CH3CH2OH and CH3OCH3.)

A) True
B) False

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Identify the dominant (strongest) type of intermolecular force present in NH3(l) .


A) Dispersion
B) Dipole-dipole
C) Ion-dipole
D) Hydrogen bonding
E) Ionic

F) A) and E)
G) A) and C)

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Indicate all the types of intermolecular forces of attraction in HF(l) .


A) Dispersion and Dipole-dipole
B) Dipole-dipole and Ionic
C) Ion-dipole and Hydrogen bonding
D) Hydrogen bonding and Dispersion
E) Dispersion

F) C) and D)
G) A) and B)

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Which one of the following substances is expected to have the highest melting point


A) CH4
B) CCl4
C) CO
D) CO2
E) C(diamond)

F) B) and C)
G) C) and D)

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Indicate all the types of intermolecular forces of attraction in CF4(g) .


A) Dispersion and Dipole-dipole
B) Dipole-dipole and Ionic
C) Ion-dipole and Hydrogen bonding
D) Hydrogen bonding and Dispersion
E) Dispersion

F) A) and E)
G) B) and D)

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The most space efficient arrangement of spheres is found in which type(s) of atom arrangement I. hexagonal close-packed II. cubic close-packed III. simple cubic IV. body-centered cubic


A) I only
B) II only
C) I and II
D) IV only
E) I, II, and IV

F) A) and C)
G) None of the above

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